Dense All?Electrochem?Active Electrodes for All?Solid?State Lithium Batteries

نویسندگان

چکیده

The energy density presents the core competitiveness of lithium (Li)-ion batteries. In conventional Li-ion batteries, utilization gravimetric/volumetric at electrode level is unsatisfactory (<84 wt% and <62 vol%, respectively) due to existence non-electrochemical active parts among 3D porous electrodes, including electrolytes, binders, carbon additives. These are regarded as indispensable irreducible components electronic ionic transport network. Here, a dense “all-electrochem-active” (AEA) for all-solid-state Li batteries proposed, which entirely constructed from family superior mixed electronic–ionic-conducting cathodes, minimize gap between accessible theoretical level. Furthermore, with ionic–electronic-conductive network self-supported AEA cathode, hybrid sulfur (S)-based exhibits high compacted filling rate 91.8%, indicates 777 W h kg?1 1945 L?1 based on total cathodes anodes when 70 °C.

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ژورنال

عنوان ژورنال: Advanced Materials

سال: 2021

ISSN: ['1521-4095', '0935-9648']

DOI: https://doi.org/10.1002/adma.202008723